Strontium nitrate

Strontium nitrate
Names
IUPAC name
Strontium nitrate
Identifiers
CAS Number
  • 10042-76-9 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 23231 checkY
ECHA InfoCard 100.030.107 Edit this at Wikidata
EC Number
  • 233-131-9
PubChem CID
  • 24848
UNII
  • BDG873AQZL checkY
CompTox Dashboard (EPA)
  • DTXSID9064924 Edit this at Wikidata
InChI
  • InChI=1S/2NO3.Sr/c2*2-1(3)4;/q2*-1;+2 checkY
    Key: DHEQXMRUPNDRPG-UHFFFAOYSA-N checkY
  • InChI=1/2NO3.Sr/c2*2-1(3)4;/q2*-1;+2
    Key: DHEQXMRUPNDRPG-UHFFFAOYAG
  • [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O
Properties
Chemical formula
Sr(NO3)2
Molar mass 211.630 g/mol (anhydrous)
283.69 g/mol (tetrahydrate)
Appearance white crystalline solid
Density 2.986 g/cm3 (anhydrous)
2.20 g/cm3 (tetrahydrate)[1]
Melting point 570 °C (1,058 °F; 843 K) (anhydrous)
100 °C, decomposes (tetrahydrate)
Boiling point 645 °C (1,193 °F; 918 K) decomposes
Solubility in water
anhydrous:
710 g/L (18 °C)
660 g/L (20 °C)
tetrahydrate:
604.3 g/L (0 °C)
2065 g/L (100 °C)
Solubility soluble in ammonia
very slightly soluble in ethanol, acetone
insoluble in nitric acid
−57.2·10−6 cm3/mol
Structure
cubic (anhydrous)
monoclinic (tetrahydrate)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Irritant
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazard OX: Oxidizer. E.g. potassium perchlorate
2
0
0
OX
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
2750 mg/kg (rat, oral)
Safety data sheet (SDS) [1]
Related compounds
Other anions
Strontium sulfate
Strontium chloride
Other cations
Beryllium nitrate
Magnesium nitrate
Calcium nitrate
Barium nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Chemical compound

Strontium nitrate is an inorganic compound composed of the elements strontium, nitrogen and oxygen with the formula Sr(NO3)2. This colorless solid is used as a red colorant and oxidizer in pyrotechnics.

Preparation

Strontium nitrate is typically generated by the reaction of nitric acid on strontium carbonate.[2]

2 HNO3 + SrCO3 → Sr(NO3)2 + H2O + CO2
The reaction of nitric acid and strontium carbonate to form strontium nitrate

Uses

Like many other strontium salts, strontium nitrate is used to produce a rich red flame in fireworks and road flares. The oxidizing properties of this salt are advantageous in such applications.[3]

Strontium nitrate can aid in eliminating and lessening skin irritations. When mixed with glycolic acid, strontium nitrate reduces the sensation of skin irritation significantly better than using glycolic acid alone.[4]

Biochemistry

As a divalent ion with an ionic radius similar to that of Ca2+ (1.13 Å and 0.99 Å respectively), Sr2+ ions resembles calcium's ability to traverse calcium-selective ion channels and trigger neurotransmitter release from nerve endings. It is thus used in electrophysiology experiments.

In popular culture

In his short story "A Germ-Destroyer", Rudyard Kipling refers to strontium nitrate as the main ingredient of the titular fumigant.

References

  1. ^ Patnaik, Pradyot (2002). Handbook of Inorganic Chemicals. McGraw-Hill, ISBN 0-07-049439-8
  2. ^ Ward, R., Osterheld, R. K., Rosenstein, R. D. (1950). "Strontium Sulfide and Selenide Phosphors". Inorganic Syntheses. Inorganic Syntheses. Vol. 3. pp. 11–23. doi:10.1002/9780470132340.ch4. ISBN 978-0-470-13234-0.
  3. ^ MacMillan, J. Paul; Park, Jai Won; Gerstenberg, Rolf; Wagner, Heinz; Köhler, Karl and Wallbrecht, Peter (2002) "Strontium and Strontium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim. doi:10.1002/14356007.a25_321
  4. ^ Zhai H, Hannon W, Hahn GS, Pelosi A, Harper RA, Maibach HI (2000). "Strontium nitrate suppresses chemically-induced sensory irritation in humans". Contact Dermatitis. 42 (2): 98–100. doi:10.1034/j.1600-0536.2000.042002098.x. PMID 10703633. S2CID 25910851.
  • v
  • t
  • e
  • SrAl2O4
  • SrB6
  • SrBr2
  • Sr(BrO3)2
  • SrCO3
  • Sr(C2H4O2)2
  • SrCl2
  • Sr(ClO3)2
  • SrCrO4
  • SrF2
  • SrI2
  • C
    6
    H
    10
    O
    6
    Sr
  • Sr(NO3)2
  • SrO
  • SrO2
  • Sr3P2
  • Sr(OH)2
  • C
    36
    H
    70
    SrO
    4
  • SrS
  • SrSe
  • SrSO4
  • SrTiO3
  • Sr3N2
  • SrRuO3
  • Sr2RuO4
  • v
  • t
  • e
Salts and covalent derivatives of the nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)4 RONO2
+CO3
+C2O4
NO3-
NH4NO3
HOONO2 FNO3
+F
Ne
NaNO3 Mg(NO3)2 Al(NO3)3
Al(NO3)4
Si P +SO4 ClONO2
+Cl
Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)2
Fe(NO3)3
Co(NO3)2
Co(NO3)3
Ni(NO3)2 CuNO3
Cu(NO3)2
Zn(NO3)2 Ga(NO3)3 Ge As +SeO3 BrNO3
+Br
Kr
RbNO3 Sr(NO3)2 Y(NO3)3 Zr(NO3)4 NbO(NO3)3 MoO2(NO3)2 Tc Ru Rh(NO3)3 Pd(NO3)2
Pd(NO3)4
AgNO3
Ag(NO3)2
Cd(NO3)2 In(NO3)3 Sn(NO3)4 Sb4O4(OH)2(NO3)2 Te INO3
+IO3
Xe(NO3)2
CsNO3 Ba(NO3)2 * Lu(NO3)3 Hf(NO3)4 TaO(NO3)3 WO2(NO3)2 ReO3NO3 Os Ir3O(NO3)10 Pt(NO3)2 Au(NO3)3 Hg2(NO3)2
Hg(NO3)2
TlNO3
Tl(NO3)3
Pb(NO3)2 Bi(NO3)3
BiO(NO3)
Po(NO3)4 At Rn
FrNO3 Ra(NO3)2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La(NO3)3 Ce(NO3)3
Ce(NO3)4
Pr(NO3)3 Nd(NO3)3 Pm(NO3)3 Sm(NO3)3 Eu(NO3)3 Gd(NO3)3 Tb(NO3)3 Dy(NO3)3 Ho(NO3)3 Er(NO3)3 Tm(NO3)3 Yb(NO3)3
** Ac(NO3)3 Th(NO3)4 PaO(NO3)3 UO2(NO3)2 Np(NO3)4 Pu(NO3)4 Am(NO3)3 Cm(NO3)3 Bk(NO3)3 Cf(NO3)3 Es Fm Md No